PTFE, FEP, and PFA Specifications
TECHNICAL DESCRIPTION
Because of its molecular structure, traditional PTFE cannot be
processed by melting, but must be compressed into shapes and heated under
pressure (sintered). In contrast, FEP and PFA are melt-processable by
conventional thermoplastic processing methods, including injection,
transfer, blow, and compression molding and by extrusion.
( see also
Generic PTFE and
Teflon® PTFE Specifications )
FEP DESCRIPTION
TetraFluorEthylene-Perfluorpropylene (FEP) is produced by
copolymerization of tetrafluoroethylene and hexafluoropropylene. It is a
relatively soft thermoplastic with lower tensile strength, wear resistance,
and creep resistance than many other engineering plastics. However, it is
chemically inert and has a low dielectric constant over a wide frequency
range. FEP possesses a very high degree of stress crack resistance, a low
coefficient of friction, exceptional dielectric properties, heat resistance,
retention of properties after service at 400°F (204°C) with useful
properties at -454°F (-270°C), and meets FDA 21CFR.177.1550.
FEP has high transparency (with good transmittance of UltraViolet and
visible wavelengths.) It has long term weatherability and excellent
resistance to ozone, sunlight and weather. FEP offers the lowest refractive
index of all thermoplastics with low light reflection (the same as water.)
Important applications are linings for pipe and chemical processing
equipment, roll covers, and numerous wire and cable applications, including
aircraft wire, plenum cable, fire alarm cable, and well logging cable.
Heat-shrinkable FEP tubing is available. FEP Film is used as glazing in
solar energy collectors.
Common FEP tradenames include Daikin Neoflon
®,
Dupont Teflon ®, and Hoechst Hostaflon
®.
PFA DESCRIPTION PerFluoroAlkoxy (PFA) offers similar properties to FEP, but is
considered more of a premium resin. PFA is preferred when extended service
is required in hostile environments involving chemical, thermal, and
mechanical stress. PFA offers high melt strength, stability at high
processing temperatures, excellent crack and stress resistance, a low
coefficient of friction, and more than 10 times the Flex life of FEP.
It has high resistance to creep and retention of properties after service at
500°F (260°C), with useful properties at -320°F (95°C). PFA also meets FDA
21CFR.177.1550.
PFA is used in the same types of applications as those listed above for FEP.
Common PFA tradenames include Daikin Neoflon ®,
Dupont Teflon ®, Hoechst Hostaflon ®,
and Ausimont Hyflon ®.
| TYPICAL PROPERTIES of SELECTED FLUOROPOLYMERS |
| ASTM or UL test |
Property |
PTFE
(unfilled) |
FEP |
PFA |
| PHYSICAL |
| D792 |
Density (lb/in³)
(g/cm³) |
0.078
2.16 |
0.078
2.15 |
0.078
2.15 |
| D570 |
Water Absorption, 24 hrs (%) |
< 0.01 |
< 0.01 |
< 0.03 |
| MECHANICAL |
| D638 |
Tensile Strength (psi) |
3,900 |
3,400 |
3,600 |
| D638 |
Tensile Elongation at Break (%) |
300 |
325 |
300 |
| D790 |
Flexural Strength (psi) |
No break |
No break |
No break |
| D2176 |
Folding Endurance (cycles) |
> 10 6 |
5-80 x 10 3 |
50-500 x 10 3 |
| D790 |
Flexural Modulus (psi) |
72,000 |
85,000 |
85,000 |
| D785 |
Hardness, Shore D |
D50 |
D56 |
D60 |
| D256 |
IZOD Notched Impact (ft-lb/in) |
3.5 |
- |
- |
| THERMAL |
| D3418 |
Melting Temp (°F / °C) |
635 / 335 |
500 / 260 |
582 / 305 |
| - |
Max Operating Temp (°F / °C) |
500 / 260 |
400 / 204 |
500 / 260 |
| UL94 |
Flammability Rating |
V-0 |
V-0 |
V-0 |
| ELECTRICAL |
| D150 |
Dielectric Constant at 1 MHz |
2.1 |
2.1 |
2.1 |
| D150 |
Dissipation Factor at 1 MHz |
< 0.0002 |
0.0007 |
0.0001 |
| D495 |
Arc Resistance (sec) |
< 300 |
< 300 |
< 180 |
| D257 |
Volume Resistivity (ohm-cm)at 50% RH |
> 10 18 |
> 10 18 |
> 10 18 |
NOTE: The information contained herein are typical values intended
for reference and comparison purposes only. They should NOT be used as a
basis for design specifications or quality control. Contact us for
manufacturers' complete material property datasheets.
All values at 73°F (23°C) unless otherwise noted.
TEFLON ® is a registered trademark of DuPont
NEOFLON is a registered trademark of Daikin America.
HOSTAFLON is a registered trademark of Hoechst Celanese.
HYFLON is a registered trademark of Ausimont USA, Inc.
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